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For the Upper East Siders of Gossip Girl, their first year of college means some hierarchical changes. At NYU, Blair (Leighton Meester) gets a cold reception from the students she was hoping to make her minions; alternately, Dan (Penn Badgley) finally hits his stride, including dating a movie star (guest star Hilary Duff) but struggling with growing feelings for his bestie Vanessa (Jessica Szohr). Serena (Blake Lively) tries various jobs in an effort to be taken seriously, but as usual ends up falling for the wrong guy and getting herself in one jam after another, the most serious of which involves her daddy issues when he (guest star William Baldwin) reappears into her family's lives. Meanwhile, Chuck (Ed Westwick) is finally happy in his relationship with Blair and, buoyed by her love, launches his own hotel to emerge from his late father's shadow. As scheming and backstabbing are the bread and butter of Gossip Girl, many villains cycle through, including Michelle Trachtenberg's return as Georgina and Desmond Harrington (Dexter) as Chuck's uncle. But the true evolving baddie in the third season is Jenny (Taylor Momsen)!